KCAL+ officially launched today, on channel 9.6; the channel's listings (via TitanTV) aren't yet listed on the CBS Los Angeles website. KCAL also has yet to straighten-out the listings of their subchannels, with the programs on KCAL+ listed on 9.2 instead of on 9.6, with the station's other subchannels (The Nest, Comet, HSN, QVC) also displayed incorrectly.
What I can tell you is that they have a three-hour game show block from 2-5pm: Funny You Should Ask, the new Flip Side, and Family Feud, with a hour of Hot Bench following from 5-6pm.
Edit: I came across program listings for KCAL+ via TVGuide.com (search for 9.6), and as PhillyWatch mentioned before, it's all extra runs of current syndicated programming from 2 and 9, and from 7pm to 4am, MeTV Toons occupies the rest of the broadcast day. Of course, MeTV Toons is already broadcast in the region over KSFV 27.1 and KAZA 54.3 full-time.